Manual Heterocycles in Natural Product Synthesis

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  1. Highly enantioselective catalytic synthesis of chiral pyridines | Nature Communications
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  3. Heterocycles In Natural Product Synthesis

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Mehta , India, working on total synthesis of complex heterocyclic natural products for nearly six years. His research interests surround on asymmetric synthesis of heterocyclic natural products of biological interest. He has co-authored nearly seventy publications and has published one review article.

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Highly enantioselective catalytic synthesis of chiral pyridines | Nature Communications

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Imidazole - Synthesis & Reactions

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This method was successfully applied to 2,4,7-trichloroquinazoline, allowing for the efficient synthesis of quinazolines bearing functionality in specific positions of the heterocyclic ring. The strategy was also extended to 1,3,6-trichloroquinoline for the synthesis and scale-up of a promising 3-aminoisoquinolin-1 2H -one inhibitor of the dual-specificity phosphatase Cdc25B.

The third section of this dissertation describes the design and synthesis of novel thieno[3,2-d]pyrimidine- and thieno[3,2-c]pyridine-based analogs for the inhibition of protein kinase D. A small library of analogs was prepared to assess the structure-activity relationship, and one analog was tested in vivo.

Heterocycles In Natural Product Synthesis

The fourth section of this dissertation discusses the investigation of an unusual alkene isomerization process, which occurred during the ring-closing metathesis for the preparation of a tricylic isoindolinone scaffold. The final section of this thesis details our work towards the synthesis of Stemona alkaloids. In particular, a second-generation approach to sessilifoliamide was achieved. The ULS Office of Scholarly Communication and Publishing fosters and supports new modes of publishing and information-sharing among researchers.